A Coordination Compound between Vanadium Oxytrichloride and Triphenyl Phosphine
نویسندگان
چکیده
منابع مشابه
Gold Coordination by a Tertiary Phosphine with Three Thioether Functions
Z. Naturforsch. 52 b, 217-220 (1997); received December 16, 1996 Gold(I) Coordination, Tris(phenylthiomethyl)phosphine, Ambidentate P/S3-Ligand The reaction of tris(phenylthiomethyl)phosphine with equimolecular amounts of [AuPPh3]+[BF4]~ affords the complex (tris(phenylthiomethyl)phosphine)(triphenylphosphine)-gold(I) tetrafluoroborate 1 in good yield. The X-ray diffraction analysis of this pro...
متن کاملCarbonyl[4-(2,6-dimethylphenylamino)pent-3-en-2-onato-κ2 N,O](triphenylphosphine-κP)rhodium(I) acetone hemisolvate
In the title compound, [Rh(C(13)H(16)NO)(C(18)H(15)P)(CO)]·0.5C(3)H(6)O, the Rh atom exhibits a square-planar coordination geometry, being coordinated by the N and O atoms of the bidentate β-diketonato ligand, a P atom from the triphenyl-phosphine unit and a C atom from the carbonyl group. The asymmetric unit also contains a disordered half-mol-ecule, lying about an inversion center, of the ace...
متن کاملcohesion and cohesive devices in a contrastive analysis between ge and esp texts
the present study was an attempt to conduct a contrastive analysis between general english (ge) and english for specific purposes (esp) texts in terms of cohesion and cohesive devices. to this end, thirty texts from different esp and ge textbooks were randomly selected. then they were analyzed manually to find the frequency of cohesive devices. cohesive devices include reference, substitution, ...
15 صفحه اولOrigin of Catalytic Activity Differences between Phosphine and Phosphine Oxide-Based Structures in the Water-Crosslinkable Polyalkoxysilane Composition
Organocatalysts have attracted enormous interest in the water-crosslinking reaction in silane-grafted polyolefins (SGPOs) system owing to their simplicity, low toxicity and environmentally benign nature compared to organotin catalysts, which are most used in SGPOs system. We focus on organophosphorus compounds including four structure types as organocatalysts; phosphoric acids, phosphoric ester...
متن کاملCarbonyl[4-(2,3-dimethylphenylamino)pent-3-en-2-onato-κ2 N,O](triphenylphosphine-κP)rhodium(I)
In the title compound, [Rh(C(13)H(16)NO)(C(18)H(15)P)(CO)], the coordination geometry of the Rh(I) atom is square-planar, formed by the coordinating N and O atoms of the bidentate enaminoketonate ligand, one C atom from the carbonyl group and a P atom from triphenyl-phosphine. The complex displays a 0.591 (3):0.409 (3) ratio disorder of the phenyl unit of the monoanionic N,O-bidentate ligand. I...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1968
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.41.1271